词条 | polymerization |
释义 | polymerization chemical reaction ![]() Two classes of polymerization usually are distinguished. In condensation polymerization, each step of the process is accompanied by formation of a molecule of some simple compound, often water. In addition polymerization, monomers react to form a polymer without the formation of by-products. Addition polymerizations usually are carried out in the presence of catalysts (catalyst), which in certain cases exert control over structural details that have important effects on the properties of the polymer. Linear polymers, which are composed of chainlike molecules, may be viscous liquids or solids with varying degrees of crystallinity; a number of them can be dissolved in certain liquids, and they soften or melt upon heating. Cross-linked polymers, in which the molecular structure is a network, are thermosetting resins (i.e., they form under the influence of heat but, once formed, do not melt or soften upon reheating) that do not dissolve in solvents. Both linear and cross-linked polymers can be made by either addition or condensation polymerization. |
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