词条 | osmosis |
释义 | osmosis chemical process ![]() If a solution is separated from the pure solvent by a membrane that is permeable to the solvent but not the solute, the solution will tend to become more dilute by absorbing solvent through the membrane. This process can be stopped by increasing the pressure on the solution by a specific amount, called the osmotic pressure. The Dutch-born chemist Jacobus Henricus van't Hoff (Hoff, Jacobus Henricus van 't) showed in 1886 that, if the solute is so dilute that its partial vapour pressure above the solution obeys Henry's law (i.e., is proportional to its concentration in the solution), then osmotic pressure varies with concentration and temperature approximately as it would if the solute were a gas occupying the same volume. This relation led to equations for determining molecular weights of solutes in dilute solutions through effects on the freezing point, boiling point, or vapour pressure of the solvent. |
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