Ionic bonding results in compounds known as ionic, or electrovalent, compounds, which are best exemplified by the compounds formed between nonmetals and the alkali and alkaline-earth metals. In ionic crystalline solids of this kind, the electrostatic forces of attraction between opposite charges and repulsion between similar charges orient the ions in such a manner that every positive ion becomes surrounded by negative ions and vice versa. In short, the ions are so arranged that the positive and negative charges alternate and balance one another, the overall charge of the entire substance being zero. The magnitude of the electrostatic forces in ionic crystals is considerable. Accordingly, these substances tend to be hard and nonvolatile.

An ionic bond is actually the extreme case of a polar covalent bond, the latter resulting from unequal sharing of electrons rather than complete electron transfer. Ionic bonds typically form when the difference in the electronegativities of the two atoms is great, while covalent bonds form when the electronegativities are similar. Compare covalent bond.