词条 | Coordination numbers and geometries of metal cyanide complexes |
释义 | Coordination numbers and geometries of metal cyanide complexes Table Coordination numbers and geometries of metal cyanide complexes electron configuration* metal ion cyanide complex geometry total number of valence electrons d2 Mo4+ 【Mo(CN)8】4− dodecahedral 18 d3 Cr3+ 【Cr(CN)6】3− octahedral 15 d4 Mn3+ 【Mn(CN)6】3− octahedral 16 d5 Fe3+ 【Fe(CN)6】3− octahedral 17 d6 Co3+ 【Co(CN)6】3− octahedral 18 d7 Co2+ 【Co(CN)5】3− square pyramidal 17 d8 Ni2+ 【Ni(CN)4】2− square planar 16 d8 Ni2+ 【Ni(CN)5】3− square pyramidal or trigonal bipyramidal 18 d10 Cd2+ 【Cd(CN)4】2− tetrahedral 18 d10 Ag+ 【Ag(CN)2】− linear 14 *Number of d electrons indicated by superscript. See as table: ![]() |
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